The efficient polymer phosphor-molybdenum additive for lubricants
https://doi.org/10.46973/0201-727X_2023_2_172
Abstract
The state diagram of the copper metaphosphate – molybdenum trioxide system, in which 2Cu(PO3)2∙4MoO3 compounds are formed, has been studied by the methods of physical and chemical analysis such as thermogravimetric, X-ray and IR-spectroscopic. The use of copper phosphoromolybdate additive to improve the physicochemical properties of greases used in friction units of railway equipment was studied. Tribotechnical tests of the created lubricants with a multifunctional additive 2Cu(PO3)2∙4MoO3 were carried out. The mechanism of the lubricating action of antiwear, extreme pressure, anticorrosion additives of copper phosphoromolybdate in model bases, which used LZ-TsNII greases, used in roller bearings of railway cars and TsIATIM-201, intended for friction units of automobile and aviation equipment, is considered.
About the Authors
M. A. SavenkovaRussian Federation
Savenkova Mariya Andreevna - Chair «Chemistry», Candidate of Chemical Sciences, Associate Professor
S. A. Volyanik
Russian Federation
Volyanik Svetlana Alekseevna - Chair «Chemistry», Candidate of Engineering Sciences, Associate Professor
A. P. Sychev
Russian Federation
Sychev Alexander Pavlovich - Candidate of Physical and Mathematical Sciences, Leading Researcher
V. V. Avilov
Russian Federation
Avilov Viktor Vladimirovich - Laboratory «Nanotechnology and New Materials», Researcher
P. G. Ivanochkin
Russian Federation
Ivanochkin Pavel Grigorievich - Chair «Theoretical Mechanics», Doctor of Engineering Sciences, Professor
References
1. Tribological studies for developing friction modifiers in the «wheel – rail» system / S. M. Zakharov, D. P. Markov, A. V. Ovechkin [et al.] // Journal of Friction and Wear. – 2015. – Vol. 36. – No. 6. – P. 468–475. – DOI: 10.3103./S10683661.
2. Properties of Puma and Buksol lubricants modified by inorganic additives of binary polyphosphates / V. I. Kolesnikov, M. A. Savenkova, V. V. Avilov [et al.] // Journal of Friction and Wear. – 2015. – Vol. 36. – No. 3. – P. 273–281. – DOI: 10.3103/S1068366615030071.
3. Improving Lubricants by Adding Inorganic Polymers / I. V. Kolesnikov, M. A. Savenkova, A. P. Sychev [et al.] // Bulletin of Mechanical Engineering. – 2021. – No. 1. – P. 329–332. – DOI: 10.3103/S1068798X21040134.
4. Synthesis and study of triboengineering characteristics of a new nanosize ceramic nickel phosphoromolybdate additive to greases / V. I. Kolesnikov, S. F. Ermakov, F. Daniel [et al.] // Journal of Friction and Wear. – 2010. – Vol. 31. – No. 6. – P. 426–432. – DOI: 10.3103/S1068366610060048.
5. Sidashov, A. V. Surface Films Formation on Steel During Friction of Polymer Composites Containing Microcapsules with Lubricant / A. V. Sidashov, M. V. Boiko // Lecture Notes in Mechanical Engineering. – 2020. – P. 1259–1268. – DOI: 10.1007/978-3-030-22041-9_131.
6. The effect of the coefficient of journal friction in «ball-and-socket» bogie body pivots on the work done by friction forces in curvilinear motion / V. I. Kolesnikov, A. A. Zarifiyan, A. P. Sychev [et al.] // Journal of Friction and Wear. – 2016. – Vol. 31. – No. 6. – P. 476–481. – DOI: 10.3103/S1068366616050081.
7. The Tribo-Induced Effect of Shielding Action of Ethanolamines and Compounds of Cholesterol under the Dynamic Contact of Metals in Plastic Lubricants / V. I. Kolesnikov, S. F. Ermakov, A. P. Sychev [et al.] // Scientific article. – 2020. – Vol. 493. – No. 1. – P. 79–83. – DOI: 10.1134/S1028335820080030.
8. Tribological Characteristics of Chemically Inactive Surfaces in Lubricants Doped with Cholesterol and Fatty Acid Compounds / S. F. Ermakov, A. P. Sychev, I. V. Kolesnikov [et al.] // Journal of Friction and Wear. – 2021. – Vol. 42. – No. 1. – P. 7–10. – DOI: 10.3103/S1068366621010025.
9. Molecularly-Engineered Lubricants : Synthesis, Activation, and Tribological Characterization of Silver Complexes as Lubricant Additives / Ch. P. Twist, A. M. Seyam, Ch. Chen [et al.] // Advanced engineering materials. – 2012. – V. 14. – P. 101–105. – DOI: 10.1002/adem.201100193.
10. Mechanism of lubricating action of polyphosphate and heteropolyphosphate additives in tribosystems / V. I. Kolesnikov, M. A. Savenkova, Y. F. Migal [et al.] // Scientific article. – 2020. – Vol. 90. – P. 743–753 (2017). – URL: https://DOI:.org/10.1134/S1070427217050135 (date of access: 05/03/2023).
11. Influence of external effects on structuring of lubricants / T.G. Chmykhova, I.O. Delikatnaya, E. N. Volnyanko // Journal of Friction and Wear. – 2010. – Vol. 28. – No. 6. – P. 634–639. – DOI: 10.3103/51068366620020051.
12. Zhang, J. Boundary lubrication by adsorption film. Friction 3 / J. Zhang, Y. Meng. – P. 115–147. (2015). – URL: https://DOI:org/10.1007/s40544015-0084-4. (date of access: 05/03/2023).
13. Formation of boundary lubricating films in the presence of complexing additives / M. V. Boiko, I. V. Kolesnikov, S. F. Ermakov [et al.] // Russian Engineering Research. – 2021. – Vol. 41. – P. 927–930. – DOI: 10.36652/0202-3350-202021-8-367-371.
14. Formation of Surface Structures under Friction in Synthetic Oils / A. V. Sidashov, M. V. Boiko, A. T. Kozakov, V. V. Lesnyak // Journal of Friction and Wear. – 2020. – Vol. 41. – No. 5. – P. 417–420. – DOI: 10.3103/S1068366620050165.
15. Study of wear particles formed in some ester lubricants / M. V. Boiko, I. V. Kolesnikov, T. G. Boiko [et al.] // AIP Conference Proceedings. – 2019. – Vol. 2188. – DOI: 10.1063/1.5138375.
Review
For citations:
Savenkova M.A., Volyanik S.A., Sychev A.P., Avilov V.V., Ivanochkin P.G. The efficient polymer phosphor-molybdenum additive for lubricants. Vestnik Rostovskogo Gosudarstvennogo Universiteta Putej Soobshcheniya. 2023;(2):172-179. (In Russ.) https://doi.org/10.46973/0201-727X_2023_2_172
JATS XML